Rare earth elements (REE) and yttrium in stream waters, stream sediments, and Fe-Mn oxyhydroxides: Fractionation, speciation, and controls over REE + Y patterns in the surface environment   总被引：1，自引：0，他引：1  

Matthew I. Leybourne  Karen H. Johannesson 《Geochimica et cosmochimica acta》2008,72(24):5962-5983

We have collected ∼500 stream waters and associated bed-load sediments over an ∼400 km² region of Eastern Canada and analyzed these samples for Fe, Mn, and the rare earth elements (REE + Y). In addition to analyzing the stream sediments by total digestion (multi-acid dissolution with metaborate fusion), we also leached the sediments with 0.25 M hydroxylamine hydrochloride (in 0.05 M HCl), to determine the REE + Y associated with amorphous Fe- and Mn-oxyhydroxide phases. We are thus able to partition the REE into “dissolved” (<0.45 μm), labile (hydroxylamine) and detrital sediment fractions to investigate REE fractionation, and in particular, with respect to the development of Ce and Eu anomalies in oxygenated surface environments. Surface waters are typically LREE depleted ([La/Sm]_NASC ranges from 0.16 to 5.84, average = 0.604, n = 410; where the REE are normalized to the North America Shale Composite), have strongly negative Ce anomalies ([Ce/Ce^∗]_NASC ranges from 0.02 to 1.25, average = 0.277, n = 354), and commonly have positive Eu anomalies ([Eu/Eu^∗]_NASC ranges from 0.295 to 1.77, average = 0.764, n = 84). In contrast, the total sediment have flatter REE + Y patterns relative to NASC ([La/Sm]_NASC ranges from 0.352 to 1.12, average = 0.778, n = 451) and are slightly middle REE enriched ([Gd/Yb]_NASC ranges from 0.55 to 3.75, average = 1.42). Most total sediments have negative Ce and Eu anomalies ([Ce/Ce^∗]_NASC ranges from 0.097 to 2.12, average = 0.799 and [Eu/Eu^∗]_NASC ranges from 0.39 to 1.43, average = 0.802). The partial extraction sediments are commonly less LREE depleted than the total sediments ([La/Sm]_NASC ranges from 0.24 to 3.31, average = 0.901, n = 4537), more MREE enriched ([Gd/Yb]_NASC ranges from 0.765 to 6.28, average = 1.97) and Ce and Eu anomalies (negative and positive) are more pronounced.The partial extraction recovered, on average ∼20% of the Fe in the total sediment, ∼80% of the Mn, and 21-29% of the REEs (Ce = 19% and Y = 32%). Comparison between REEs in water, partial extraction and total sediment analyses indicates that REEs + Y in the stream sediments have two primary sources, the host lithologies (i.e., mechanical dispersion) and hydromorphically transported (the labile fraction). Furthermore, Eu appears to be more mobile than the other REE, whereas Ce is preferentially removed from solution and accumulates in the stream sediments in a less labile form than the other REEs + Y. Despite poor statistical correlations between the REEs + Y and Mn in either the total sediment or partial extractions, based on apparent distribution coefficients and the pH of the stream waters, we suggest that either sediment organic matter and/or possibly δ-MnO₂/FeOOH are likely the predominant sinks for Ce, and to a lesser extent the other REE, in the stream sediments.  相似文献   

Church-based social capital, networks and geographical scale: Katrina evacuation, relocation, and recovery in a New Orleans Vietnamese American community     

Christopher A. Airriess  Wei Li  Karen J. Leong  Angela Chia-Chen Chen  Verna M. Keith 《Geoforum》2008,39(3):1333-1346

This research examines the role of social capital and networks to explain the evacuation, relocation, and recovery experiences of a Vietnamese American community in New Orleans, Louisiana in the aftermath of Hurricane Katrina. As the single largest community institution, the parish church’s complex bonding and bridging social capital and networks proved particularly critical in part because of its historically based ontological security. The process of evacuation, but especially relocation and recovery, was dependent on deploying co-ethnic social capital and networks at a variety of geographical scales. Beyond the local or community scale, extra-local, regional, and national scales of social capital and networks reproduced a spatially redefined Vietnamese American community. Part of the recovery process included constructing discursive place-based collective-action frames to successfully contest a nearby landfill that in turn engendered social capital and networks crossing ethnic boundaries to include the extra-local African American community. Engaging social capital and networks beyond the local geographical scale cultivated a Vietnamese American community with an emergent post-Katrina cultural and political identity.  相似文献   

Size scales over which ordinary chondrites and their parent asteroids are homogeneous in oxidation state and oxygen-isotopic composition   总被引：1，自引：0，他引：1  

Alan E. Rubin  Karen Ziegler 《Geochimica et cosmochimica acta》2008,72(3):948-958

Literature data demonstrate that on a global, asteroid-wide scale (plausibly on the order of 100 km), ordinary chondrites (OC) have heterogeneous oxidation states and O-isotopic compositions (represented, respectively, by the mean olivine Fa and bulk Δ¹⁷O compositions of equilibrated samples). Samples analyzed here include: (a) two H5 chondrite Antarctic finds (ALHA79046 and TIL 82415) that have the same cosmic-ray exposure age (7.6 Ma) and were probably within ∼1 km of each other when they were excavated from the H-chondrite parent body, (b) different individual stones from the Holbrook L/LL6 fall that were probably within ∼1 m of each other when their parent meteoroid penetrated the Earth’s atmosphere, and (c) drill cores from a large slab of the Estacado H6 find located within a few tens of centimeters of each other. Our results indicate that OC are heterogeneous in their bulk oxidation state and O-isotopic composition on 100-km-size scales, but homogeneous on meter-, decimeter- and centimeter-size scales. (On kilometer size scales, oxidation state is heterogeneous, but O isotopes appear to be homogeneous.) The asteroid-wide heterogeneity in oxidation state and O-isotopic composition was inherited from the solar nebula. The homogeneity on small size scales was probably caused in part by fluid-assisted metamorphism and mainly by impact-gardening processes (which are most effective at mixing target materials on scales of ?1 m).  相似文献   

Aspects of conservation in the excavation site of the Athribis temple in Egypt     

Hans Leisen  Esther von Plehwe-Leisen  Christina Verbeek  Christine Jürgens  Sabine Krause 《Environmental Geology》2008,56(3-4):689-697

  相似文献   

Das Präkambrium Finnlands     

Ferdinand von Wolff 《International Journal of Earth Sciences》1932,23(2):89-122

Ohne ZusammenfassungDer vorliegende Aufsatz berichtet über die wissenschaftlichen Ergebnisse der Tagung der Internationalen Vereinigung zum Studium des Präkambriums in Helsingfors im Juli 1931, hinzugefügt sind einige ergänzende Betrachtungen zum Rappakiwiproblem.  相似文献   

Der geologische Bau und die tektonische Bedeutung der Balearischen Inseln     

W. von Seidlitz 《International Journal of Earth Sciences》1927,18(4):308-320

Ohne ZusammenfassungVortrag auf der Hauptversammlung in Frankfurt a. M. am 8. Jan. 1927.  相似文献   

Die West-Mecklenburgische Senke     

Kurd von Bülow 《International Journal of Earth Sciences》1938,29(7-8):575-583

Ohne Zusammenfassung  相似文献   

Osteuropa und die zyklische Gliederung der Erdgeschichte     

Serge von Bubnoff 《International Journal of Earth Sciences》1949,37(1):60-71

Zusammenfassung Die epirogenetische Geschichte Osteuropas (Fennosarmatiens) läßt sich seit dem Kambrium in 11 Zyklen der Transgression und Regression gliedern, die vermutlich den PulsationenGrabaus entsprechen. Bei im allgemeinen gleichzeitigem und gleichsinnigem Verlauf zeigen sich regional gewisse Unterschiede oder Phasendifferenzen, indem einige stabilere Teile Sarmatiens die einzelnen Zyklen nur verzögert oder überhaupt nicht mitmachen. Diese Pulsationen sind nicht identisch mit den vom Verf. angenommenen Großzyklen Westeuropas, sondern werden von ihnen überlagert, allerdings in regelmäßiger Weise, derart, daß mehrere Pulsationen einen Großzyklus zusammensetzen. Durch diese Überlagerung entstehen Phasendivergenzen, welche den Gesamtvorgang komplizieren, ohne seine Gesetzmäßigkeit aufzuheben. Eine dritte Ursache für regionale Unterschiede besteht in dem vom Verf. schon früher betonten zyklischen Abdrehen der tektogenetischen Beanspruchung, welche zwischen alpidisch und uralisch wechselt. Da, entsprechend dem Großgefüge, im Westen die alpidische, im Osten die uralische Bewegungstendenz vorwiegt, entstehen zwangsläufig zeitliche Differenzen, die zu einer weiteren Komplikation des Bildes beitragen. Der Verf. legt aber Wert auf die Feststellung, daß diese Differenzen und Komplikationen in dem Wesen der zyklischen Prozesse begründet sind und ihre Gesetzmäßigkeit nicht nur nicht aufheben, sondern im Gegenteil dazu dienen können, die tieferen Ursachen des erdgeschichtlichen Rhythmus zu ergründen.  相似文献   

Die Bedeutung der Versumpfung für die Entstehung von Hochmooren in Deutschland     

Kurd von Bülow 《International Journal of Earth Sciences》1935,26(4):277-284

Zusammenfassung Es ist nur bei Gebirgsmooren zulässig, von Versumpfungsmooren zu reden. Die als solche erscheinenden Hochmoore des Flachlandes dürften in der Mehrzahl der Fälle keine Versumpfungsmoore im engeren Sinne sein, sondern nur durch Versumpfugserscheinungen in ihrer Ausbreitung geförderte Hochmoore, die ursprünglich als Hochmoore auf eutrophen und mesotrophen Moorschichten begannen (sogen. kombinierte Profile).Das Vorhandensein von Hochmooren des Flachlandes, die wirklich durch Versumpfung ins Leben gerufen worden sind, ist erst noch zu beweisen.  相似文献   

Chlorinated hydrocarbons and hatching success in Baltic herring spring spawners     

P.-D Hansen  H von Westernhagen  H Rosenthal 《Marine environmental research》1985,15(1):59-76

Eggs from 69 females of spring spawning herring from the German Baltic coast (Travemünde, April 1979) were incubated in clean sea water (20‰ S, temperature 8°C) under standard conditions. Sixty-one trials could be used for the evaluation of hatching success. Viable hatch was taken as a measure to evaluate the effects of chlorinated hydrocarbons accumulated in gonads, liver and muscle of parental fish.PCB levels in running ripe females ranged on a wet weight basis between 19 and 241 ng g^?1 (gonad), 20 and 377 ng g^?1 (liver) and 11 and 1820 ng g^?1 (muscle). Concentrations of other chlorinated hydrocarbons (DDD, DDE, γ-HCH, etc.) were in the same range as reported by other authors for Baltic herring (Huschenbeth, 1973, 1977). Viable hatch was significantly affected at ovary DDE concentrations higher than 18 ng g^?1 (wet wt) and PCB concentrations of more than 120 ng g^?1 (wet wt).Results are compared with data obtained during earlier investigations with flounder eggs.  相似文献